So it was no wonder she took a motherly shine to a young fan who greeted her at the Russian premiere of her new film last night.
Angelina, 35, was signing autographs and chatting to fans outside the Moscow screening of spy thriller Salt when she spotted the young girl leaning towards her.
Maternal instinct: Angelina Jolie kisses a young fan who greeted her at the Moscow premiere of her new movie Salt
Common touch: The actress seemed to put the girl at ease despite being one of the most famous people in the world
Her
maternal instinct kicked in as she stood next to the girl, who looked a
little overwhelmed by the crush of people pushing photos and cameras in
her idols face as they waited in the 35degree heat.
But her nerves turned to delight as Angelina touched her cheek to reassure her and then leaned in and gave her a gentle kiss on the cheek.
But her nerves turned to delight as Angelina touched her cheek to reassure her and then leaned in and gave her a gentle kiss on the cheek.
The actress would not doubt have been reminded about her six children - Maddox, 8, Pax, 6, Zahara, 5, Shiloh, 4, and two-year-old twins Knox and Vivienne - waiting for her at home.
Scarlet lady: Angelina's flowing red gown was a departure from the her usual favourite black
Going solo: Angelina cut a solitary figure on the red carpet as the only star of the film to attend the Moscow premiere
Melee: Hundreds of fans and photographers had turned out to the actress
Angelina delighted fans with 'dobry vecher' which is Russian for 'good evening'
She looked stunning in the flowing scarlet frock as she chatted to fans and posed on the red carpet outside the city's Oktyabr cinema.
Inside, she greeted the press and the audience with a cheery, 'dobry vecher', which is Russian for 'good evening'.
Stunning: Angelina's tight-fitting red dress accentuated her toned figure
Spekaing at a press conference she held earlier in the day in a building right in front of the city's famous Red Square, she said: 'You don't want to focus on the negative behind this issue of the spy swap because I think that what is happening between our countries is wonderful these days, so many positive movements forward.'
Room with a view: Angelina had a photo call at the Moscow Ritz Carlton hotel, with the Red Square with the Kremlin and Saint Basil's Cathedral in the background